Ions in a binary asymmetric dipolar mixture: mole fraction dependent Born energy of solvation and partial solvent polarization structure.

Abstract

Mean spherical approximation (MSA) for electrolyte solution has been extended to investigate the role of partial solvent polarization densities around an ion in a completely asymmetric binary dipolar mixture. The differences in solvent diameters, dipole moments, and ionic size are incorporated systematically within the MSA framework in the present theory… (More)

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@article{Kashyap2007IonsIA, title={Ions in a binary asymmetric dipolar mixture: mole fraction dependent Born energy of solvation and partial solvent polarization structure.}, author={Hemant K Kashyap and Ranjit Biswas}, journal={The Journal of chemical physics}, year={2007}, volume={127 18}, pages={184502} }