Ionic chemistry of tetravinylsilane cation (TVS+) formed by electron impact: theory and experiment.


We performed experimental and ab initio studies on tetravinylsilane cation (TVS(+)) and its ionic and neutral fragmentation products. The aim of the study is the assignment of the products formed in electron impact ionization reaction of TVS. The experimental data were compared with ab initio data calculated at the MP2/cc-pVDZ level of theory. We found good… (More)
DOI: 10.1021/jp901978j


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