Ion exchange separation of strontium and rubidium on Dowex 50W-X8, using the complexation properties of EDTA and DCTA
@article{Vorster2008IonES, title={Ion exchange separation of strontium and rubidium on Dowex 50W-X8, using the complexation properties of EDTA and DCTA}, author={C. Vorster and T. Walt and P. Coetzee}, journal={Analytical and Bioanalytical Chemistry}, year={2008}, volume={392}, pages={287-296} }
A chromatographic method for separation of strontium from rubidium, using the unique alkaline-earth metal complexation ability of the carboxylic acids EDTA and DCTA is proposed. The method was developed in order to improve the effectiveness of 87Sr/86Sr isotope studies with ICP–QMS. Due to the isobaric overlap of 87Rb with 87Sr, strontium needs to be separated from rubidium prior to sample analysis with ICP–QMS. The method involves the retention of strontium, calcium, magnesium, and rubidium on… CONTINUE READING
Figures, Tables, and Topics from this paper
5 Citations
Elemental Profile and 87Sr/86Sr Isotope Ratio as Fingerprints for Geographical Traceability of Wines: an Approach on Romanian Wines
- Chemistry
- Food Analytical Methods
- 2016
- 18
Adsorption of strontium from aqueous solution by silica mesoporous SBA-15
- Chemistry
- Journal of Radioanalytical and Nuclear Chemistry
- 2014
- 7
87 sr/ 86 sr ratio in vineyard soils from Portuguese denominations of origin and its potential for origin authentication
- Environmental Science
- 2014
- 13
- Highly Influenced
- PDF
Radiostrontium and radium analysis in low-level environmental samples following a multi-stage semi-automated chromatographic sequential separation.
- Chemistry, Medicine
- Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine
- 2011
- 22
Tracing changes in atmospheric sources of lead contamination using lead isotopic compositions in Australian red wine.
- Environmental Science, Medicine
- Chemosphere
- 2016
- 17
References
SHOWING 1-10 OF 24 REFERENCES
Comparative distribution coefficients and cation-exchange behaviour of the alkaline earth elements with various complexing agents.
- Chemistry, Medicine
- Talanta
- 1970
- 17
ICP-MS determination of strontium isotope ratio in wine in order to be used as a fingerprint of its regional origin
- Chemistry
- 2001
- 122
Extraction separation of 86Rb from 85Sr in trace level with 18-crown-6 in nitrobenzene
- Chemistry
- 2002
- 7
Large volume injection in ion chromatography Separation of rubidium and strontium for on-line inductively coupled plasma mass spectrometry determination of strontium isotope ratios.
- Chemistry, Medicine
- Journal of chromatography. A
- 2007
- 15