Ion association and solvation behavior of tetraalkylammonium iodides in binary mixtures of dichloromethane + N,N-dimethylformamide probed by a conductometric study.

@article{Bhattacharjee2010IonAA,
  title={Ion association and solvation behavior of tetraalkylammonium iodides in binary mixtures of dichloromethane + N,N-dimethylformamide probed by a conductometric study.},
  author={Arijit Bhattacharjee and Mahendra Nath Roy},
  journal={Physical chemistry chemical physics : PCCP},
  year={2010},
  volume={12 43},
  pages={14534-42}
}
Precise measurements on electrical conductances of tetraalkylammonium iodides, R(4)NI (R = n-butyl to n-heptyl), in different mass% (0-100) of dichloromethane (DCM) + N,N-dimethylformamide (DMF) at 298.15 K have been performed. Limiting molar conductances (Λ(0)), association constants (K(A)) and co-sphere diameter (R) for ion-pair formation in the mixed… CONTINUE READING