Investigation of the typical triangular structure B3 in boron chemistry: insight into bare all-boron clusters used as ligands or building blocks.

Abstract

Even though boron clusters are quite significant, bare boron clusters as ligands in chemical compounds are still unknown. Triangular B(3) is a key constituent of all-boron clusters and widely applied in the boron compounds. As a basic step toward understanding the assembly and stabilization of bare all-boron clusters and the possibility of their fusion… (More)

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