Investigation of selectivity in reversed-phase liquid chromatography-effects of stationary and mobile phases on retention of homologous series

@article{Colin1983InvestigationOS,
  title={Investigation of selectivity in reversed-phase liquid chromatography-effects of stationary and mobile phases on retention of homologous series},
  author={Henri Colin and Ante Krstulovic and Marie-France Gonnord and Georges Guiochon and Zheng Yun and Pavel Jandera},
  journal={Chromatographia},
  year={1983},
  volume={17},
  pages={9-15}
}
SummaryExtrapolation of log k'vs. nc plots for homologous series chromatographed with different mobile phases leads to a common intersection point. Its coordinates depend on the series and the solvent used, and can be rationalized on the basis of the retention model of interaction indices.The existence of this convergence point is reflected in the linear relationship of logα-logβ, which permits the optimization of chromatographic separations in the region of solvent compositions where these two… CONTINUE READING