Investigation of a new bis(carboxylate)triazole-based anchoring ligand for dye solar cell chromophore complexes.

@article{Sinopoli2017InvestigationOA,
  title={Investigation of a new bis(carboxylate)triazole-based anchoring ligand for dye solar cell chromophore complexes.},
  author={Alessandro Sinopoli and Fiona A. Black and Christopher J. Wood and Elizabeth A. Gibson and Paul I P Elliott},
  journal={Dalton transactions},
  year={2017},
  volume={46 5},
  pages={
          1520-1530
        }
}
A novel anchoring ligand for dye-sensitised solar cell chromophoric complexes, 1-(2,2'-bipyrid-4-yl)-1,2,3-triazole-4,5-dicarboxylic acid (dctzbpy), is described. The new dye complexes [Ru(bpy)2(dctzbpy)][PF6]2 (AS16), [Ir(ppy)2(dctzbpy)][PF6] (AS17) and [Re(dctzbpy)(CO)3Cl] (AS18) were prepared in a two stage procedure with intermediate isolation of their diester analogues, AS16-Et2, AS17-Et2 and AS18-Et2 respectively. Electrochemical analysis of AS16-Et2, AS17-Et2 and AS18-Et2 reveal… Expand
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