Intramolecular electron transfer in cyanide bridged adducts comprising Ru(II)/Ru(III) tetracarboxylate and [Mn(I)(CO)(CN)((t)BuNC)(4)] units.

Abstract

Reaction of mixed valence ruthenium tetracarboxylates [Ru(2)(II,III)(R(1)COO)(2)(R(2)COO)(2)Cl] (R(1) = Me, R(2) = 2,4,6-(i)Pr-Ph or R(1) = R(2) = (t)Bu) with two equivalents of the octahedral manganese complex [Mn(I)(CO)(CN)((t)BuNC)(4)] leads to the formation of cyanide bridged heteronuclear coordination compounds of the general formula {[Ru(2)(II,III)(R… (More)
DOI: 10.1039/b923536a

Topics

Cite this paper

@article{Imhof2010IntramolecularET, title={Intramolecular electron transfer in cyanide bridged adducts comprising Ru(II)/Ru(III) tetracarboxylate and [Mn(I)(CO)(CN)((t)BuNC)(4)] units.}, author={Wolfgang Imhof and Anke Sterzik and Sven Krieck and Markus Schwierz and Thomas Hoffeld and Eike T Spielberg and Winfried Plass and Nathan J. Patmore}, journal={Dalton transactions}, year={2010}, volume={39 27}, pages={6249-54} }