Interpreting the H / D Isotope Fractionation of Liquid Water during Evaporation without Condensation

@inproceedings{CappaInterpretingTH,
  title={Interpreting the H / D Isotope Fractionation of Liquid Water during Evaporation without Condensation},
  author={Christopher D Cappa and Jared D. Smith and Walter S Drisdell and Richard J Saykally and Ronald C. Cohen}
}
A theoretical model of liquid water evaporation has been developed to interpret results from a recent experimental investigation of isotope fractionation during free evaporation [Cappa et al. J. Phys. Chem. B 2005, 109 (51),24391]. It is established that the free evaporation isotope fractionation factors ( Revap) are primarily influenced by the nature of the intermolecular interactions between water molecules, namely, the condensed phase hindered translational and librational frequencies at the… CONTINUE READING
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