Interpreting effects of structure variations induced by temperature and pressure on luminescence spectra of platinum(II) bis(dithiocarbamate) compounds.


Luminescence spectra of two square-planar dithiocarbamate complexes of platinum(II) with different steric bulk, platinum(II) bis(dimethyldithiocarbamate) (Pt(MeDTC)2) and platinum(II) bis(di(o-pyridyl)dithiocarbamate) (Pt(dopDTC)2), are presented at variable temperature and pressure. The spectra show broad d-d luminescence transitions with maxima at… (More)
DOI: 10.1021/ic5025718


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