Interfacial interactions and complex segmental dynamics in systems based on silica-polydimethylsiloxane core–shell nanoparticles: Dielectric and thermal study

@inproceedings{Klonos2015InterfacialIA,
  title={Interfacial interactions and complex segmental dynamics in systems based on silica-polydimethylsiloxane core–shell nanoparticles: Dielectric and thermal study},
  author={Panagiotis A. Klonos and I.Ya. Sulym and Mykola Vasyl'ovych Borysenko and Vlad M Gun'ko and Sotiria Kripotou and Apostolos Kyritsis and Polycarpos Pissis},
  year={2015}
}
Effects of two types of silica particles, with different characteristics of porosity, on segmental mobility of poly(dimethylsiloxane), PDMS, in coreeshell nanocomposites with two contents of polymer, 40 and 80 wt%, were studied by employing thermal (DSC) and dielectric (DRS, TSDC) techniques, under different annealing procedures. Filler morphology and polymereparticle interactions were found to affect PDMS crystallinity and segmental mobility. The dielectric techniques allowed the detection of… CONTINUE READING
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