Interconversions of clusters in the Pd(O), CO, P(n-Alk)3 system

@article{Mednikov1982InterconversionsOC,
  title={Interconversions of clusters in the Pd(O), CO, P(n-Alk)3 system},
  author={Eugenii G. Mednikov and N. K. Eremenko},
  journal={Bulletin of the Academy of Sciences of the USSR, Division of chemical science},
  year={1982},
  volume={31},
  pages={2240-2245}
}
  • Eugenii G. Mednikov, N. K. Eremenko
  • Published 1982
  • Chemistry
  • Conclusions1.In a Pd(O), CO, P(n-Alk)3 system, using PBu3 as an example, interconversions of compounds Pd10(CO)14 (P Bu3)4, Pd10(CO)12(P Bu3)6, Pd4(CO)5(PBu3)4, Pd(CO)(P Bu3)3, and Pd(P Bu3)4 reversibly take place.2.Increase in the degree of polynuclearity of the carbonyltrialkylphosphine clusters of palladium can be attained by binding phosphine into a protonated or other form.3.In the equilibrium system Pd(0), CO, P(n-Alk)3, the most stable clusters are Pd10(CO)14(PBu3)4, Pd10(CO)12L6, Pd4(CO… CONTINUE READING

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