Interconversion between formic acid and H(2)/CO(2) using rhodium and ruthenium catalysts for CO(2) fixation and H(2) storage.


The interconversion between formic acid and H(2)/CO(2) using half-sandwich rhodium and ruthenium catalysts with 4,4'-dihydroxy-2,2'-bipyridine (DHBP) was investigated. The influence of substituents of the bipyridine ligand was studied. Chemical shifts of protons in bipyridine linearly correlated with Hammett substituent constants. In the hydrogenation of CO… (More)
DOI: 10.1002/cssc.201000327

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