• DOI:10.1103/PHYSREVB.83.054116
• Corpus ID: 53314056

Interatomic potential for the Al-Cu system

@article{Apostol2011InteratomicPF,
  title={Interatomic potential for the Al-Cu system},
  author={Florin Apostol and Yuri Mishin},
  journal={Physical Review B},
  year={2011},
  volume={83}
}

• F. Apostol, Y. Mishin
• Published 25 February 2011
• Materials Science
• Physical Review B

An angular-dependent interatomic potential has been developed for the Al-Cu system based on existing embedded-atom method potentials for Al and Cu and fitting of the cross-interaction functions to experimental and first-principles data. The potential reproduces lattice parameters, formation energies, and elastic constants of the θ and θ ′ phases of this system. It predicts the θ ′ phase to be more stable than θ at 0 K but to become less stable at hight temperatures due to vibrational entropy. The temperate and entropy of this phase transformation are in good agreement with previous first-principles calculations [C. Wolverton and V. Ozoliņs, Phys. Rev. Lett. 86, 5518 (2001)]. The potential provides a reasonable description of the phase stability across the Al-Cu phase diagram, dilute heats of solution, and other thermodynamic properties. It has also been tested for generalized stacking fault energies in the presence of a copper layer embedded in Al. This configuration bears some resemblance to Guinier-Preston zones that strengthen Al-Cu alloys. The trends predicted by the potential for uniform shearing of this configuration are in agreement with results of first-principles density-functional calculations performed in this work. The potential is expected to be suitable for atomistic simulations of precipitation hardening of Al-Cu alloys.