Interactions between SF4 and Fluoride: A Crystallographic Study of Solvolysis Products of SF4·Nitrogen-Base Adducts by HF.

@article{Goettel2016InteractionsBS,
  title={Interactions between SF4 and Fluoride: A Crystallographic Study of Solvolysis Products of SF4·Nitrogen-Base Adducts by HF.},
  author={James T Goettel and Nathan Kostiuk and Michael Gerken},
  journal={Inorganic chemistry},
  year={2016},
  volume={55 14},
  pages={7126-34}
}
Adducts between SF4 and a nitrogen base are easily solvolyzed by HF, yielding the protonated nitrogen base and fluoride. Salts resulting from the solvolysis of SF4·NC5H5, SF4·NC5H4(CH3), SF4·NC5H3(CH3)2, and SF4·NC5H4N(CH3)2 have been studied by Raman spectroscopy and X-ray crystallography. Crystal structures were obtained for pyridinium salts [HNC5H5(+)]F… CONTINUE READING