Interaction of I(-) and I(3)(-) with a redox-stable Cr(III)-based structural surrogate for photo-oxidized "N3 Dye".

Abstract

A series of [Cr (L)(2)(NCS)(2)]X complexes, where L = 2,2'-bipyridine (bpy) or 4,4'-dimethyl-2,2'-bipyridine (dmb) and X(-) is I(-), I(3)(-), or NO(3)(-), have been prepared for study as redox-inactive surrogates for diisothiocyanatobis(2,2'-bipyridine-4,4'-dicarboxylic acid)ruthenium(III) ("N3(+)"). Dilute solution spectra in dichloromethane or… (More)

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