Insight into silicate-glass corrosion mechanisms.

@article{Cailleteau2008InsightIS,
  title={Insight into silicate-glass corrosion mechanisms.},
  author={C{\'e}line Cailleteau and Fr{\'e}d{\'e}ric Angeli and François Devreux and St{\'e}phane Gin and Jacques Jestin and Patrick Jollivet and Olivier Spalla},
  journal={Nature materials},
  year={2008},
  volume={7 12},
  pages={978-83}
}
The remarkable chemical durability of silicate glass makes it suitable for a wide range of applications. The slowdown of the aqueous glass corrosion kinetics that is frequently observed at long time is generally attributed to chemical affinity effects (saturation of the solution with respect to silica). Here, we demonstrate a new mechanism and highlight the impact of morphological transformations in the alteration layer on the leaching kinetics. A direct correlation between structure and… CONTINUE READING

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References

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Showing 1-10 of 60 references

A review

  • Conradt, R. Chemical durability of oxide glasses in aqueous solutions
  • J. Am. Ceram. Soc. 91, 728–735
  • 2008

Chemical durability of oxide glasses in aqueous solutions : A review

  • R. Conradt
  • J . Am . Ceram . Soc .
  • 2008

Influence of zirconium on the structure of pristine and leached soda - lime borosilicate glasses : Towards a quantitative approach by 17 O MQMAS NMR

  • F. Angeli, M. Gaillard, T. Charpentier, P. Jollivet
  • J . Non - Cryst . Solids
  • 2008

Theoretical consideration on the application of the Aagaard-Helgeson rate law to the dissolution of silicate minerals and glasses

  • S. Gin, C. Jégou, P. Frugier, Y. Minet
  • Chem. Geol. 255,
  • 2008

Towards a quantitative approach by 17O MQMAS NMR

  • F. Angeli, M. Gaillard, T. Charpentier, Jollivet, P. Influence of zirconium on the structure of pristine, leached soda-lime borosilicate glasses
  • J. Non-Cryst. Solids 354, 3713–3722
  • 2008

Accelerated weathering of a high-level and pu-bearing lanthanide borosilicate waste glass in a can-in-canister configuration

  • Pierce, M E.
  • Appl. Geochem
  • 2007

Solid state diffusion during nuclear glass residual alteration in solution

  • T. Chave, P. Frugier, A. Ayral, S. Gin
  • J. Nucl. Mater. 362,
  • 2007

Water di ff usion in the simulated French nuclear waste SON 68 contacting silica rich solutions : Experimental and modeling

  • K. Ferrand, A. Abdelouas, B. Grambow
  • J . Nucl . Mater .
  • 2006

Leaching of borosilicate glasses

  • F. Devreux, A. Ledieu, P. Barboux, Y. Minet
  • II. Model and Monte Carlo simulations. J. Non…
  • 2004

Leaching of borosilicate glasses . I . Experiments

  • A. Ledieu, F. Devreux, P. Barboux, L. Sicard, O. Spalla
  • J . Non - Cryst . Solids
  • 2004

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