Insight into Compounds with Cu(H2O)62+ Units: New Ideas for Understanding Cu2+ in Tutton Salts

@article{Aramburu2019InsightIC,
  title={Insight into Compounds with Cu(H2O)62+ Units: New Ideas for Understanding Cu2+ in Tutton Salts},
  author={Jos{\'e} Antonio Aramburu and Arghya Bhowmik and Juan Mar{\'i}a Garc{\'i}a‐Lastra and Pablo Garc{\'i}a-Fern{\'a}ndez and Miguel Moreno},
  journal={The Journal of Physical Chemistry C},
  year={2019}
}
In the last 65 years the properties of Tutton salts containing Cu2+ cations have been interpreted on the basis of elongated complexes induced by a static Jahn–Teller effect (JTE). Through the analysis of experimental data and the results of first-principles calculations, we show here that such an idea, though widely followed, is not correct. By contrast, this work proves that the local geometry of Cu(H2O)62+ units in Tutton salts actually arises from a compressed octahedron although hidden by… 
12 Citations
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