Insertion and substitution chemistry at the boron fourth position in charge-neutral zwitterionic tripodal tris(methimazolyl)borate ligands.

Abstract

A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B-N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and… (More)
DOI: 10.1021/ic202618p

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@article{Bailey2012InsertionAS, title={Insertion and substitution chemistry at the boron fourth position in charge-neutral zwitterionic tripodal tris(methimazolyl)borate ligands.}, author={Philip J. Bailey and Nicola L. Bell and Gary S Nichol and Simon Parsons and Fraser J. White}, journal={Inorganic chemistry}, year={2012}, volume={51 6}, pages={3677-89} }