Infrared spectrum and stability of a pi-type hydrogen-bonded complex between the OH and C2H2 reactants.

Abstract

A hydrogen-bonded complex between the hydroxyl radical and acetylene has been stabilized in the reactant channel well leading to the addition reaction and characterized by infrared action spectroscopy in the OH overtone region. Analysis of the rotational band structure associated with the a-type transition observed at 6885.53(1) cm(-1) (origin) reveals a T… (More)

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Cite this paper

@article{Davey2004InfraredSA, title={Infrared spectrum and stability of a pi-type hydrogen-bonded complex between the OH and C2H2 reactants.}, author={James B Davey and Margaret E. Greenslade and Mark D Marshall and Marsha I Lester and Martyn D Wheeler}, journal={The Journal of chemical physics}, year={2004}, volume={121 7}, pages={3009-18} }