Infrared Spectrum and Vibrational Assignment for Chlorine Monoxide, Cl2O

@article{Rochkind1965InfraredSA,
  title={Infrared Spectrum and Vibrational Assignment for Chlorine Monoxide, Cl2O},
  author={M. Rochkind and G. Pimentel},
  journal={Journal of Chemical Physics},
  year={1965},
  volume={42},
  pages={1361-1368}
}
  • M. Rochkind, G. Pimentel
  • Published 1965
  • Chemistry
  • Journal of Chemical Physics
  • Infrared studies of chlorine monoxide (16O and 18O) in the region 200–4000 cm−1 for both gas and condensed phases are presented. The spectra require reassignment of the stretching fundamentals and reveal the previously unknown bending fundamental. The new assignment (solid phase: v1=630.7, v2=296.4, v3=670.8 cm−1) results in a new value for the Cl–O bond stretching force constant, Kr=2.75 mdyn/A, which is strikingly lower than values previously cited. The bond in chlorine monoxide is proposed… CONTINUE READING
    37 Citations