Influence of the polymerisation time on the porous and chromatographic properties of monolithic poly(1,2-bis(p-vinylphenyl))ethane capillary columns.

@article{Greiderer2009InfluenceOT,
  title={Influence of the polymerisation time on the porous and chromatographic properties of monolithic poly(1,2-bis(p-vinylphenyl))ethane capillary columns.},
  author={Andreas Greiderer and Lukas Trojer and Christian W Huck and Guenther Karl Bonn},
  journal={Journal of chromatography. A},
  year={2009},
  volume={1216 45},
  pages={7747-54}
}
In order to elucidate the effect of the polymerisation time on the morphology of styrene based monolithic support materials, continuous poly(1,2-bis(p-vinylphenyl))ethane (BVPE) rods were synthesised in 1.0ml glass vials by thermally initiated free radical polymerisations of BVPE in the presence of porogens (toluene, decanol) and a,a'-azoisobutyronitrile (AIBN) as initiator at 65 degrees C for different polymerisation times (60, 90, 150, 300 and 600min). Porosity parameters like pore-size… CONTINUE READING