Influence of position of substituent groups on removal of chlorophenols and cresols by horseradish peroxidase and determination of optimum conditions.

@article{Yamada2007InfluenceOP,
  title={Influence of position of substituent groups on removal of chlorophenols and cresols by horseradish peroxidase and determination of optimum conditions.},
  author={Kazunori Yamada and Takashi Shibuya and Masashi Noda and Nozomi Uchiyama and Ayumi Kashiwada and Kiyomi Matsuda and Mitsuo Hirata},
  journal={Bioscience, biotechnology, and biochemistry},
  year={2007},
  volume={71 10},
  pages={2503-10}
}
Enzymatic treatment of o-, m-, and p-chlorophenols and o-, m-, and p-cresols from artificial wastewater was undertaken through the enzymatic conversion into the corresponding phenoxy radicals with horseradish peroxidase (HRP) and nonenzymatic radical coupling reaction. The concentration of chlorophenols and cresols decreased sharply over the reaction time and water-insoluble oligomer precipitates were generated. The optimum conditions were determined to be the H2O2 concentration of 2.5 mM and… CONTINUE READING

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