Influence of homologous disaccharides on the hydrogen-bond network of water: complementary Raman scattering experiments and molecular dynamics simulations.

@article{Lerbret2005InfluenceOH,
  title={Influence of homologous disaccharides on the hydrogen-bond network of water: complementary Raman scattering experiments and molecular dynamics simulations.},
  author={Adrien Lerbret and Patrice Bordat and F Affouard and Yannic Guinet and Alain H{\'e}doux and Laurent Paccou and Dominique Pr{\'e}vost and M. N. Descamps},
  journal={Carbohydrate research},
  year={2005},
  volume={340 5},
  pages={881-7}
}
A comparative investigation of trehalose, sucrose, and maltose in water solution has been performed using Raman scattering experiments and Molecular Dynamics simulations. From the analysis of the O-H stretching region in the [2500,4000] cm(-1) Raman spectral range, which includes for the first time the contribution of 'free' water, and the statistical distribution of water HB probabilities from MD simulations, this study confirms the privileged interaction of trehalose with water above a… CONTINUE READING

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