Influence of conformational changes on spin crossover properties and superstructure formation in 2D coordination polymers [Fe(hbtz)2(RCN)2](ClO4)2.

Abstract

2D structurally related iron(ii) coordination networks {[Fe(hbtz)2(RCN)2](ClO4)2}∞ featuring, besides tetrazol-2-yl rings in the first coordination sphere, also axially coordinated propionitrile or allyl cyanide molecules (R = C3H5-, 1; R = C2H5-, 2) were synthesized. Thermally induced spin crossover (SCO) in 1 takes place in two poorly resolved stages (T(1… (More)
DOI: 10.1039/c5dt03249k

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Cite this paper

@article{Ksiek2015InfluenceOC, title={Influence of conformational changes on spin crossover properties and superstructure formation in 2D coordination polymers [Fe(hbtz)2(RCN)2](ClO4)2.}, author={Maria Książek and Joachim Kusz and Agata Białońska and Robert Bronisz and Marek Weselski}, journal={Dalton transactions}, year={2015}, volume={44 42}, pages={18563-75} }