Influence of Bridgehead Substitution and Ring Annelation on the Photophysical Properties of Polycyclic DBO-Type Azoalkanes.

Abstract

The photophysical data for the polycyclic, bridgehead-substituted derivatives 1-10 of the photoreluctant diazabicyclo[2.2.2]oct-2-ene (DBO) are presented. Substitution on the bridgehead positions with radical-stabilizing substituents enhances the photoreactivity (Phi(r)) and decreases the fluorescence quantum yields (Phi(f)) and lifetimes (tau) compared to… (More)

Cite this paper

@article{Adam1999InfluenceOB, title={Influence of Bridgehead Substitution and Ring Annelation on the Photophysical Properties of Polycyclic DBO-Type Azoalkanes.}, author={Waldemar Adam and Achim Nikolaus and J{\"{u}rgen Sauer}, journal={The Journal of organic chemistry}, year={1999}, volume={64 10}, pages={3695-3698} }