In situ synthesis of Ni(OH)2 nanobelt modified electroactive poly(vinylidene fluoride) thin films: remarkable improvement in dielectric properties.

Abstract

A facile and low cost synthesis of Ni(OH)2 nanobelt (NB) modified electroactive poly(vinylidene fluoride) (PVDF) thin films with excellent dielectric properties has been reported via in situ formation of Ni(OH)2 NBs in the PVDF matrix. The formation and morphology of the NBs are confirmed by UV-visible spectroscopy and field emission scanning electron microscopy respectively. A remarkable improvement in electroactive β phase nucleation (∼82%) and the dielectric constant (ε ∼ 3.1 × 10(6) at 20 Hz) has been observed in the nanocomposites (NCs). The interface between the NBs and the polymer matrix plays a crucial role in the enhancement of the electroactive β phase and the dielectric properties of thin films. Strong interaction via hydrogen bonds between Ni(OH)2 NBs and the PVDF matrix is the main reason for enhancement in β phase crystallization and improved dielectric properties. The NC thin films can be utilized for potential applications as high energy storage devices like supercapacitors, solid electrolyte batteries, self-charging power cells, piezoelectric nanogenerators, and thin film transistors and sensors.

DOI: 10.1039/c5cp01207d

Cite this paper

@article{Thakur2015InSS, title={In situ synthesis of Ni(OH)2 nanobelt modified electroactive poly(vinylidene fluoride) thin films: remarkable improvement in dielectric properties.}, author={Pradip Thakur and Arpan Kool and Biswajoy Bagchi and Nur Amin Hoque and Sukhen Das and Papiya Nandy}, journal={Physical chemistry chemical physics : PCCP}, year={2015}, volume={17 19}, pages={13082-91} }