In situ observations of gas phase dynamics during graphene growth using solid-state carbon sources.
@article{Kwak2013InSO,
title={In situ observations of gas phase dynamics during graphene growth using solid-state carbon sources.},
author={Jinsung Kwak and Taesoon Kwon and Jae Hwan Chu and Jae-Kyung Choi and Mi-Sun Lee and Sung Youb Kim and Hyung-Joon Shin and Kibog Park and Jang‐Ung Park and Soon‐Yong Kwon},
journal={Physical chemistry chemical physics : PCCP},
year={2013},
volume={15 25},
pages={
10446-52
}
}A single-layer graphene has been uniformly grown on a Cu surface at elevated temperatures by thermal processing of a poly(methyl methacrylate) (PMMA) film in a rapid thermal annealing (RTA) system under vacuum. The detailed chemistry of the transition from solid-state carbon to graphene on the catalytic Cu surface was investigated by performing in situ residual gas analysis while PMMA/Cu-foil samples were being heated, in conjunction with interrupted growth studies to reconstruct ex situ the…
19 Citations
Solid-Phase Coalescence of Electrochemically Exfoliated Graphene Flakes into a Continuous Film on Copper
- Materials Science
- 2016
The ability to directly synthesize high-quality graphene patterns over large areas is important for many applications such as electronic and optoelectronic devices and circuits. Here, we report a…
Conversion of Langmuir-Blodgett monolayers and bilayers of poly (amic acid) through polyimide to graphene
- Materials Science
- 2016
Various solid carbon sources, particularly poly(methyl methacrylate), have been used as precursors to graphene. The corresponding growth process generally involves the decomposition of the solids to…
Graphene quantum dots and fullerenol as new carbon sources for single–layer and bi–layer graphene synthesis by rapid thermal annealing method
- Chemistry, Physics
- 2017
Ammonia sensors based on in situ fabricated nanocrystalline graphene field-effect devices
- Chemistry2018 13th International Conference on Design & Technology of Integrated Systems In Nanoscale Era (DTIS)
- 2018
By evaluation of the input characteristics of the ncGFET under different volume concentrations of ammonia, a global increase in the conductivity is observed, which influences the sensitivity of the devices as well as of the negative shift of the charge neutrality point.
CVD growth of 1D and 2D sp2 carbon nanomaterials
- ChemistryJournal of Materials Science
- 2015
The discovery of graphene and carbon nanotubes (rolled-up graphene) has excited the world because their extraordinary properties promise tremendous developments in many areas. Like any materials with…
A Facile Route for Patterned Growth of Metal-Insulator Carbon Lateral Junction through One-Pot Synthesis.
- Materials ScienceACS nano
- 2015
One-pot synthesis of graphene/amorphous carbon (a-C) heterostructures from a solid source of polystyrene via selective photo-cross-linking process is reported, confirming the reliable quality of graphene and well-defined graphene/ a-C interface.
High-rate synthesis of graphene by a lower cost chemical vapor deposition route
- PhysicsJournal of Nanoparticle Research
- 2017
Chemical vapor deposition (CVD) reaction from metal particles to produce graphene has seldom been reported so far. In this paper, the CVD growth of graphene was conducted under ambient pressure…
Formation of 3D graphene–Ni foam heterostructures with enhanced performance and durability for bipolar plates in a polymer electrolyte membrane fuel cell
- Materials Science, Engineering
- 2018
Improving the lifetime and the operational stability of polymer electrolyte membrane fuel cells (PEMFCs) is critical for realizing their implementation as a practical and highly-efficient energy…
References
SHOWING 1-10 OF 36 REFERENCES
Facile synthesis of few-layer graphene with a controllable thickness using rapid thermal annealing.
- Materials ScienceACS applied materials & interfaces
- 2012
It was found that the evaporation of oxygen atoms from the surface is the dominant factor affecting the formation of graphene films, and the resulting films have a limited thickness, even for an extended RTA time.
Graphene growth by a metal-catalyzed solid-state transformation of amorphous carbon.
- Materials Science, ChemistryACS nano
- 2011
It is shown that the transformation of the energetically less favorable amorphous carbon to the more favorable phase of graphene occurs by diffusion of carbon atoms through the catalytically active metal.
Graphene growth using a solid carbon feedstock and hydrogen.
- PhysicsACS nano
- 2011
The possibility of obtaining graphene using amorphous-carbon thin films, without and with hydrogen gas added is explored, and a large area, uniform monolayer graphene obtained had electron and hole mobilities of 2520 and 2050 cm(2) V(-1) s(-1), respectively.
Graphene Thickness Control via Gas-Phase Dynamics in Chemical Vapor Deposition
- Physics
- 2012
Graphene has attracted intense research interest due to its exotic properties and potential applications. Chemical vapor deposition (CVD) on Cu foils has shown great promises for macroscopic growth…
Near room-temperature synthesis of transfer-free graphene films.
- Materials ScienceNature communications
- 2012
A new method for the synthesis of graphene films directly on SiO(2)/Si substrates, even plastics and glass at close to room temperature (25-160 °C), which opens up new possibilities for the fabrication of multiple nanoelectronic devices.
Growth of graphene from solid carbon sources
- Chemistry, PhysicsNature
- 2010
It is demonstrated that large area, high-quality graphene with controllable thickness can be grown from different solid carbon sources—such as polymer films or small molecules—deposited on a metal catalyst substrate at temperatures as low as 800 °C.
Synthesis of graphene on silicon dioxide by a solid carbon source.
- Materials ScienceNano letters
- 2010
The presented approach allows for mass fabrication of polycrystalline graphene without transfer steps while using only CMOS compatible process steps.
In Situ TEM Studies of Metal–Carbon Reactions
- Materials ScienceMicroscopy and Microanalysis
- 2002
In situ TEM studies show the mechanism to be of the dissolution-precipitation type, which is equivalent to the metal-mediated crystallization process for amorphous silicon and germanium.
High-yield production of graphene by liquid-phase exfoliation of graphite.
- Chemistry, PhysicsNature nanotechnology
- 2008
Graphene dispersions with concentrations up to approximately 0.01 mg ml(-1), produced by dispersion and exfoliation of graphite in organic solvents such as N-methyl-pyrrolidone are demonstrated.
Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide.
- PhysicsNature materials
- 2009
The new growth process introduced here establishes a method for the synthesis of graphene films on a technologically viable basis and produces monolayer graphene films with much larger domain sizes than previously attainable.