In-ESI source hydrogen/deuterium exchange of carbohydrate ions.

Abstract

We present the investigation of hydrogen/deuterium (H/D) exchange of carbohydrates ions occurring in the electrospray ion source. The shape of the deuterium distribution was observed to be considerably dependent on the temperature of the ion transfer tube and the solvent used. If deuterated alcohol (EtOD or MeOD) or D2O/deuterated alcohol is used as an… (More)
DOI: 10.1021/ac4038202

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