Impact of environmentally induced fluctuations on quantum mechanically mixed electronic and vibrational pigment states in photosynthetic energy transfer and 2D electronic spectra.

@article{Fujihashi2015ImpactOE,
  title={Impact of environmentally induced fluctuations on quantum mechanically mixed electronic and vibrational pigment states in photosynthetic energy transfer and 2D electronic spectra.},
  author={Yuta Fujihashi and G. Fleming and A. Ishizaki},
  journal={The Journal of chemical physics},
  year={2015},
  volume={142 21},
  pages={
          212403
        }
}
  • Yuta Fujihashi, G. Fleming, A. Ishizaki
  • Published 2015
  • Medicine, Chemistry, Physics
  • The Journal of chemical physics
    • Recently, nuclear vibrational contribution signatures in two-dimensional (2D) electronic spectroscopy have attracted considerable interest, in particular as regards interpretation of the oscillatory transients observed in light-harvesting complexes. These transients have dephasing times that persist for much longer than theoretically predicted electronic coherence lifetime. As a plausible explanation for this long-lived spectral beating in 2D electronic spectra, quantum-mechanically mixed… CONTINUE READING
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