Identifying the Hydrogenated Planar Tetracoordinate Carbon: A Combined Experimental and Theoretical Study of CAl4H and CAl4H.

@article{Xu2017IdentifyingTH,
  title={Identifying the Hydrogenated Planar Tetracoordinate Carbon: A Combined Experimental and Theoretical Study of CAl4H and CAl4H.},
  author={Jing Xu and Xinxing Zhang and Shuang Yu and Yi-Hong Ding and Kit H Bowen},
  journal={The journal of physical chemistry letters},
  year={2017},
  volume={8 10},
  pages={
          2263-2267
        }
}
The chemical curiosity "planar tetracoordinate carbon" (ptC) has greatly broadened one's knowledge of molecular bonding motifs apart from the traditional, tetrahedral, van't Hoff and LeBel's concept. Synthesized ptC examples have been reported either in the solid state or in the gas phase, where the ptC core is usually metalized or organometallized. Surprisingly, there has been no experimental report on hydrogenated ptC to date. A possible answer to this situation could be the "promiscuity" of… CONTINUE READING
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