Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework.

@article{Li2014HydrothermalCO,
  title={Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework.},
  author={Xin-Xiong Li and Wei-hui Fang and Jun-Wei Zhao and Guo-Yu Yang},
  journal={Chemistry},
  year={2014},
  volume={20 52},
  pages={17324-32}
}
Three novel hexa-Ni-substituted Dawson phosphortungstates [Ni6 (en)3 (H2O)6 (μ3-OH)3 (H3 P2 W15 O56 )]⋅14 H2O (1), [Ni(enMe)2 (H2O)][Ni6 (enMe)3 (μ3-OH)3 (H2O)6 (HP2 W15 O56)]⋅ 10 H2O (2), and [Ni(enMe)2 ]3 [Ni(enMe)2 (H2O)][Ni(enMe)(H2O)2][Ni6 (enMe)3 (μ3-OH)3 (Ac)2 (H2O)(P2 W15 O56)]2 ⋅6 H2O (3) (en=ethylenediamine, enMe=1, 2-diaminopropane, Ac=CH3 COO… CONTINUE READING