Corpus ID: 203926073

Hydrothermal Synthesis and Structure Characterization of an Acidic Cerium Sulfate Hydrate,H_3O[Ce(SO_4)_2(H_2O)_3] H_2O

@article{Xin2005HydrothermalSA,
  title={Hydrothermal Synthesis and Structure Characterization of an Acidic Cerium Sulfate Hydrate,H_3O[Ce(SO_4)_2(H_2O)_3] H_2O},
  author={Mh Xin and Y Wang and Gs Zhu and J. Sun and M. Xue and Fx Sun and Qr Fang and G. Tian and X. Guo and S. Qiu},
  journal={Chemical Research in Chinese Universities},
  year={2005}
}
  • Mh Xin, Y Wang, +7 authors S. Qiu
  • Published 2005
  • Chemistry
  • Chemical Research in Chinese Universities
An acidic cerium sulfate hydrate,H_(3)O[Ce(SO_(4))_(2)(H_(2)O)_(3)] H_(2)O,was hydrothermally synthesized and characterized by single crystal X-ray diffraction.The compound crystallizes in monoclinic system,space group P2_(1)/c with cell parameters: a=0.677 8(3) nm,b=1.908 2(7) nm,c=0.882 7(3) nm,β=97.332(7)°,V=1.115 5(7) nm~3,Z=4,R_(1)=0.029 5,wR_(2)=0.065 0,GOF=0.974.It possesses a layered anion framework constructed of CeO_(9) tetradecahedra and SO_(4) tetrahedra with H_(3)O~(+) ion and H_(2… Expand