Hydrophobic hydration and the anomalous partial molar volumes in ethanol-water mixtures.

Abstract

The anomalous behavior in the partial molar volumes of ethanol-water mixtures at low concentrations of ethanol is studied using molecular dynamics simulations. Previous work indicates that the striking minimum in the partial molar volume of ethanol VE as a function of ethanol mole fraction XE is determined mainly by water-water interactions. These results… (More)
DOI: 10.1063/1.4906750

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