Hydrolysis of Diaryliodonium Salts

@article{Caserio1959HydrolysisOD,
  title={Hydrolysis of Diaryliodonium Salts},
  author={Marjorie C. Caserio and Donald L. Glusker and John D. Roberts},
  journal={Journal of the American Chemical Society},
  year={1959},
  volume={81},
  pages={336-342}
}
The products of hydrolysis of some unsymmetrically substituted diphenyliodonium salts to phenols and aryl iodides have been identified and their distributions determined. The direction of cleavage has been found to be insensitive to the nature of the substituents, the solvent, catalysts, and the nature of the associated anion, fluoride, fluoroborate, p-toluenesulfonate or trifluoroacetate. A rate study has shown that hydrolysis is a complex reaction which is retarded by acid and catalyzed by… Expand
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