Terpenic acyclic tertiary' acetylene alcohol dehydrolinatool (DHL, 3,7-dimethyl-3-hydroxy-6-octaen-l-yne) i s used for linalool (LN, 3,7-dimethyl-3-hydroxy-1,6-octadiene) synthesis by hydrogenation of the triple bond to a double bond. Linalool is an aromatic substance of the terpene series; these compounds are used in the production of cosmetics and perfume compositions . DHL hydrogenation over metals of group Vlll is known from the literature . The maximum selectivity is possessed by Pd catalyst deposited on alumina (0.5% Pd/7-Ab_O3) and modified by heavy metal salts and organic and inorganic bases [21. Data are available on the hydrogenation of the acetylene alcohol triple bond to a double bond over Pal-containing polymer catalyst . Palladium polymer catalysts, which can be also used for linalool preparation, offer a number of advantages compared to conventional Pd / AI203 catalysts: high mechanical strength and absence of modifying additives chemical poisons. In this paper we study the optimum conditions for dehydrolinalool hydrogenation over Pd-containing polymer catalyst and the kinetics and mechanism of this reaction.