Hydrogenation of benzene to cyclohexane catalyzed by rhodium(I) complex supported on montmorillonite clay

@article{Halligudi1992HydrogenationOB,
  title={Hydrogenation of benzene to cyclohexane catalyzed by rhodium(I) complex supported on montmorillonite clay},
  author={Shivappa B. Halligudi and Hari C Bajaj and K. N. Bhatt and M. Krishnaratnam},
  journal={Reaction Kinetics and Catalysis Letters},
  year={1992},
  volume={48},
  pages={547-552}
}
Abstract[Rh(I)PPh3]+ intercelated in the interlamellars of montmorillonite clay catalyzes the hydrogenation of benzene to cyclohexane at 70°C and 20 atm hydrogen pressure.Abstract[Rh(I)PPh3)]+, добавленный к прослойкам глины монтморил-лонита, катализирет гидрирование бензола до циклогек-сана при 70°C и давлении водорода −20 атм. 
View on Springer
21 Citations
Background Citations
2
Methods Citations
1

21 Citations

Citation Type

Citation Type

Hydrogenation reactions on heterogenized Wilkinson complexes
A novel clay catalyst containing a heterogenized Rh(I) triphenylphosphine complex (Rh-bentonite) has been prepared via ion exchange of a Hungarian Na+-bentonite with Wilkinson complex [RhCl(PPh3)3].… Expand
Hydrogenation of benzene on Ni/Al-pillared montmorillonite catalysts
Abstract Ni on Al-pillared montmorillonite systems were prepared and tested as hydrogenation catalysts using hydrogenation of benzene as a test reaction. Catalytic activity was evaluated over a… Expand
Hydrogenation of benzene on Ni/Al-pillared saponite catalysts
Abstract Benzene hydrogenation has been employed as a test reaction for examining Nickel on Al-pillared saponite systems as hydrogenation catalysts. Catalytic activity was evaluated over a… Expand
Photocatalytic hydrogen production based on a water-soluble porphyrin derivative as sensitizer and a series of Wilkinson type complexes as catalysts
Herein, we report photochemical hydrogen evolution systems consisting of various rhodium based catalysts with Wilkinson type structures, Zn metalated porphyrins and fluorescein as photosensitizers… Expand
Synthesis, Spectral and Thermo Analytical Studies of Nickel (II) and Ruthenium (II) Complexes of Schiff Base Ligands for Hydrogenation of Benzene
Novel Nickel(II) and Ruthenium(II) complexes of schiff base ligands were syn- thesized and studied using various spectral and thermoanalytical techniques. One of the
Mesoporous catalyst of Co/MWCNTs as an effective catalyst in toluene hydrogenation and data analysis using response surface methodology (RSM)
Abstract Co/MWCNTs and Co/AC catalysts with high loading of Co (about 45%) were prepared through the wet impregnation method from cobalt nitrate hexahydrate. The synthesized catalysts characterized… Expand
Preparation of Organophilic Pd–Montmorillonite, An Efficient Catalyst in Alkyne Semihydrogenation
Abstract Palladium particles incorporated into organophilic montmorillonite (Pd–M) were prepared via a novel synthetic method, mediated by a cationic surfactant stabilizer. The materials were… Expand
Benzene hydrogenation over highly active monodisperse Ru/γ-Al2O3 nanocatalyst synthesized by (w/o) reverse microemulsion
Ruthenium nanoparticles (10–40 nm) were synthesized by the reduction of aqueous ruthenium trichloride in aqueous sodium borohydride by the water-in-oil (w/o) reverse microemulsion method at… Expand
A study of hydrogen pressure during hydropyrolysis of Miscanthus x giganteus and online catalytic vapour upgrading with Ni on ZSM-5
Abstract Hydropyrolysis, coupled with a secondary catalytic reactor was used as a method of producing a bio-oil from Miscanthus x giganteus with low levels of oxygenated compounds and high yields of… Expand
Electrochemical behaviour and electrowinning of rhodium in acidic chloride solution
The electrochemical behaviour and recovery of rhodium in an acidic solution were investigated using a rotating disc electrode system and a modified electrochemical cyclone cell, respectively. The… Expand
...
1
2
3
...

References

SHOWING 1-4 OF 4 REFERENCES
The first catalytic hydrogenation of natural oils at ambient condition by an intercalated ruthenium complex in montmorillonite
Abstract The ruthenium(IV) dihydrido species [RuCl 2 (H) 2 AsPh 3 ) 2 ] obtained by the hydrogenation of RuCl 3 (AsPh 3 ) 2 ·CH 3 OH intercalated in the interlamellars of montmorillonite clay… Expand
Stereoselective homogeneous hydrogenation of arenes to cyclohexanes catalysed by [Rh(η5-C5Me5)Cl2]2
[Rh(η5-C5Me5)Cl2]2 catalyses the hydrogenation of benzene and a variety of substituted benzenes to the appropriate cyclohexanes under homogeneous conditions (50 °C, 50 atm) in the presence of base… Expand
Dinuclear arene hydrido-complexes of ruthenium(II): reactions with olefins and catalysis of homogeneous hydrogenation of arenes
The dinuclear hydrido-complex [(η6-C6Me6)Ru(µ-H)2(µ-Cl)Ru(η6-C6Me6)]Cl reacts with mono-olefins to give the corresponding alkanes and either η3-allylruthenium(II) or dieneruthenium(0) complexes; it… Expand
A stable .mu.-peroxo complex of rhodium(II) intercalated in the interlamellar spaces of montmorillonite. Solid-state aluminum-27, silicon-29 and phosphorus-31 NMR and ESR investigation
Formation of the {mu}-peroxo Rh(II) complex by the oxygenation of cationic (Rh(PPh{sub 3}){sub 3}){sup +} species trapped in the hydration layer of montomorillonite is reported herein. The complex… Expand