Hydrogenation of benzene to cyclohexane catalyzed by rhodium(I) complex supported on montmorillonite clay

@article{Halligudi1992HydrogenationOB,
  title={Hydrogenation of benzene to cyclohexane catalyzed by rhodium(I) complex supported on montmorillonite clay},
  author={Shivappa B. Halligudi and Hari C Bajaj and K. N. Bhatt and M. Krishnaratnam},
  journal={Reaction Kinetics and Catalysis Letters},
  year={1992},
  volume={48},
  pages={547-552}
}
Abstract[Rh(I)PPh3]+ intercelated in the interlamellars of montmorillonite clay catalyzes the hydrogenation of benzene to cyclohexane at 70°C and 20 atm hydrogen pressure.Abstract[Rh(I)PPh3)]+, добавленный к прослойкам глины монтморил-лонита, катализирет гидрирование бензола до циклогек-сана при 70°C и давлении водорода −20 атм. 
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22 Citations
Background Citations
3
Methods Citations
1

22 Citations

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References

SHOWING 1-4 OF 4 REFERENCES

The first catalytic hydrogenation of natural oils at ambient condition by an intercalated ruthenium complex in montmorillonite

Stereoselective homogeneous hydrogenation of arenes to cyclohexanes catalysed by [Rh(η5-C5Me5)Cl2]2

[Rh(η5-C5Me5)Cl2]2 catalyses the hydrogenation of benzene and a variety of substituted benzenes to the appropriate cyclohexanes under homogeneous conditions (50 °C, 50 atm) in the presence of base…

Dinuclear arene hydrido-complexes of ruthenium(II): reactions with olefins and catalysis of homogeneous hydrogenation of arenes

The dinuclear hydrido-complex [(η6-C6Me6)Ru(µ-H)2(µ-Cl)Ru(η6-C6Me6)]Cl reacts with mono-olefins to give the corresponding alkanes and either η3-allylruthenium(II) or dieneruthenium(0) complexes; it…

A stable .mu.-peroxo complex of rhodium(II) intercalated in the interlamellar spaces of montmorillonite. Solid-state aluminum-27, silicon-29 and phosphorus-31 NMR and ESR investigation

Formation of the {mu}-peroxo Rh(II) complex by the oxygenation of cationic (Rh(PPh{sub 3}){sub 3}){sup +} species trapped in the hydration layer of montomorillonite is reported herein. The complex…