Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine—Rh System.

@article{Kawamorita2009HydrogenationOH,
  title={Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine—Rh System.},
  author={Soichiro Kawamorita and Go Hamasaka and Hirohisa Ohmiya and Kenji Hara and Atsushi Fukuoka and Masaya Sawamura},
  journal={ChemInform},
  year={2009},
  volume={40}
}
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Research on synthesis and thermodynamic properties of 2-methoxycyclohexanol

Abstract2-Methoxycyclohexanol is synthesized through an alcoholysis reaction of cyclohexene oxide and methanol with Ag2CsPW12O40 as catalyst. The elemental analyzer, FT-IR, GC, and NMR are used to…

References

Hydrogenation of hindered ketones catalyzed by a silica-supported compact phosphine-Rh system.

A heterogeneous mono(phosphine)-Rh catalyst system silica-SMAP-Rh(OMe)(cod) showed broad applicability toward the hydrogenation of hindered ketones, Doubly alpha-branched ketones such as diisopropyl ketone was hydrogenated under nearly atmospheric conditions.