Hydrogenation of Condensed Aromatic Compounds over Mesoporous Bifunctional Catalysts Following a Diels–Alder Adduct Pathway

  title={Hydrogenation of Condensed Aromatic Compounds over Mesoporous Bifunctional Catalysts Following a Diels–Alder Adduct Pathway},
  author={Pham Thanh Huyen and Marko Krivec and Marijan Ko{\vc}evar and Ioana Cristina Bucur and Cristina Rizescu and Vasile I. P{\^a}rvulescu},
Pt(0.5 wt %)‐Al‐SBA‐15 and Pt(0.5 wt %)‐Al‐MCM‐41 bifunctional catalysts were prepared by wet impregnation and investigated in the hydrogenation of anthracene and the hydrogenolysis/hydrogenation of a series of synthesized Diels–Alder adducts with anthracene and anthracene derivatives. The mesoporous texture of the investigated catalysts allowed the hydrogenation of these substrates to a large extent. In direct correlation with the size of the Pt particles, Pt‐Al‐SBA‐15 exhibited a higher… Expand
9 Citations
Synergistic B Al interaction in SBA-15 affording an enhanced activity for the hydro-isomerization of heptane over Pt B Al-SBA-15 catalysts
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Promoting effects of desilication and dealumination on the catalytic performance of Al-rich HMOR for catalysing naphthalene tert-butylation with tertiary butanol
  • Zhihua Huang, Jie Zhang, +5 authors Lei Xu
  • Chemistry
  • Applied Catalysis A: General
  • 2019
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In this work, the mesoporous material Al-B-SBA-15 has been obtained by direct synthesis method with Si : B : Al ratio of 10 : 0.5 : 0.5. Wetness impregnation (WI) method was used to load platinum onExpand
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Ordered, bimodal mesoporous CMK-5 carbon is prepared by using mesoporous SBA-15 silica as a structural mold. The carbon material is chemically modified by oxidative treatment with acidic persulfateExpand
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The synthesis of propellanes containing bicyclo[2.2.2]octene via olefin metathesis approach is less explored. Herein, we describe a simple and convenient method to synthesize propellane derivativesExpand
Emission-Tunable Amorphous Room-Temperature Phosphorescent Polymers Based on Thermoreversible Dynamic Covalent Bond.
A new method to rationally design and synthesize emission-tunable organic RTP materials via dynamic covalent bonds through Diels-Alder reaction, a [4+2] cycloaddition reaction between dienes and dienophiles is provided. Expand
ZSM-5/SBA-15 versus Al-SBA-15 as supports for the hydrocracking/hydroisomerization of alkanes
This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant number 104.05-2014.21. CM aknowledges financial support by the SpanishExpand


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Abstract The hydrogenation of tetralin, naphthalene, and phenanthrene as individual feed components and in diesel model feeds has been studied over a series of mono- and bimetallic Pt and PdExpand
Carbon-supported Pd nanoparticles as catalysts for anthracene hydrogenation
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