Hydrogen bonding in the ethanol-water dimer.


We report the first rotational spectrum of the ground state of the isolated ethanol-water dimer using chirped-pulse Fourier transform microwave spectroscopy between 8-18 GHz. With the aid of isotopic substitutions, and ab initio calculations, we identify the measured conformer as a water-donor/ethanol-acceptor structure. Ethanol is found to be in the gauche conformation, while the monomer distances and orientations likely reflect a cooperation between the strong (O-HO) and weak (C-HO) hydrogen bonds that stabilizes the measured conformer. No other conformers were assigned in an argon expansion, confirming that this is the ground-state structure. This result is consistent with previous vibrationally-resolved Raman and infrared work, but sheds additional light on the structure, due to the specificity of rotational spectroscopy.

DOI: 10.1039/c5cp03589a

6 Figures and Tables

Cite this paper

@article{Finneran2015HydrogenBI, title={Hydrogen bonding in the ethanol-water dimer.}, author={Ian A Finneran and P. Brandon Carroll and Marco A Allodi and Geoffrey A . Blake}, journal={Physical chemistry chemical physics : PCCP}, year={2015}, volume={17 37}, pages={24210-4} }