Hydrogen Peroxide Coordination to Cobalt(II) Facilitated by Second-Sphere Hydrogen Bonding.

@article{Wallen2016HydrogenPC,
  title={Hydrogen Peroxide Coordination to Cobalt(II) Facilitated by Second-Sphere Hydrogen Bonding.},
  author={Christian M Wallen and Lukas Palatinus and John Bacsa and Christopher C Scarborough},
  journal={Angewandte Chemie},
  year={2016},
  volume={55 39},
  pages={
          11902-6
        }
}
M(H2 O2 ) adducts have been postulated as intermediates in biological and industrial processes; however, only one observable M(H2 O2 ) adduct has been reported, where M is redox-inactive zinc. Herein, direct solution-phase detection of an M(H2 O2 ) adduct with a redox-active metal, cobalt(II), is described. This Co(II) (H2 O2 ) compound is made observable… CONTINUE READING