Hydrogen-Bonded Molecular Ribbons as Templates for the Synthesis of Modified Mineral Phases This work was supported by the ICI Strategic Research Fund, the EPSRC, and the Wellcome Trust.

@article{Champ2000HydrogenBondedMR,
  title={Hydrogen-Bonded Molecular Ribbons as Templates for the Synthesis of Modified Mineral Phases This work was supported by the ICI Strategic Research Fund, the EPSRC, and the Wellcome Trust.},
  author={Champ and Dickinson and Fallon and Heywood and Mascal},
  journal={Angewandte Chemie},
  year={2000},
  volume={39 15},
  pages={
          2716-2719
        }
}
  • Champ, Dickinson, Mascal
  • Published 4 August 2000
  • Materials Science, Chemistry
  • Angewandte Chemie
The combination of two important organizational principles, that is surfactant monolayer assembly and the triazinetriamine - triazinetrione hydrogen-bonding molecular ribbon, produces a hybrid assembly which is used as a novel template to control the orientation and morphology in the crystallization of calcium carbonate. 
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References

SHOWING 1-10 OF 49 REFERENCES
Biomimetic Mineralization in and on Polymers
Biological mineralization leads to the development of finely scaled, highly controlled inorganic precipitates in organic matrixes. It was initially thought that this control was mainly exercised
Crystallization of Calcite Spherules around Designer Nuclei.
Gold colloids modified with p-sulfanylphenol self-assembled monolayers provide novel nanoscopic seeds for the nucleation of calcium and strontium carbonate from aqueous solution. The morphologies of
Crystal Tectonics: Construction of Reticulated Calcium Phosphate Frameworks in Bicontinuous Reverse Microemulsions
TLDR
The resulting materials represent replicas of the microemulsion architecture, but the pore sizes are incommensurate, suggesting that secondary modifications in the bicontinuous microstructure occur during crystal growth.
Total Alignment of Calcite at Acidic Polydiacetylene Films: Cooperativity at the Organic-Inorganic Interface
TLDR
These results indicate the kinds of interactions that may occur in biological systems where large arrays of crystals are co-aligned.
Synthesis of inorganic materials with complex form
Recent developments in inorganic materials chemistry suggest that concepts such as morphogenesis, replication, self-organization and metamorphosis could be useful for devising new synthetic
Porphyrin Amphiphiles as Templates for the Nucleation of Calcium Carbonate
The processes of biogenic crystal growth are of interest both to derive an understanding of the biochemistry for the development of mesoscopic structures and as an inspiration to devise new
Sol−Gel Synthesis of Organized Matter
In this review, we describe four approaches to the materials synthesis of organized inorganic matter. These include the use of self-assembled organic templates (transcriptive synthesis), cooperative
Templated Growth of Calcite, Vaterite, and Aragonite Crystals on Self-Assembled Monolayers of Substituted Alkylthiols on Gold
Making use of extensive scanning electron microscopy and the Rietveld analysis of X-ray diffraction profiles, we have studied the morphology, crystal habits and phase compositions of crystals of
Biomimetic Pathways for Assembling Inorganic Thin Films
TLDR
The ability to process ceramic-organic nanocomposite films by these methods provides new technological opportunities.
Biomimetic Materials Chemistry
  • S. Mann
  • Materials Science, Chemistry
  • 1995
Partial table of contents: Biomineralization and Biomimetic Chemistry. Biogenic Cadmium Sulfide Semiconductors. Biomimetic Approaches to Nanoscale Fabrication. Construction of Organized Particulate
...
...