Hydricity of an Fe-H Species and Catalytic CO2 Hydrogenation.

Abstract

Despite renewed interest in carbon dioxide (CO2) reduction chemistry, examples of homogeneous iron catalysts that hydrogenate CO2 are limited compared to their noble-metal counterparts. Knowledge of the thermodynamic properties of iron hydride complexes, including M-H hydricities (ΔGH(-)), could aid in the development of new iron-based catalysts. Here we… (More)
DOI: 10.1021/ic502508p

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