Honeycombs, herringbones and brick-walls; three-fold guest-dependent variation in copper trimesate complexes bearing sulfimide ligands.

@article{Holmes2004HoneycombsHA,
  title={Honeycombs, herringbones and brick-walls; three-fold guest-dependent variation in copper trimesate complexes bearing sulfimide ligands.},
  author={Kathryn E Holmes and Paul F. Kelly and Mark R J Elsegood},
  journal={Dalton transactions},
  year={2004},
  volume={21},
  pages={3488-94}
}
Reaction of a solution of CuSO(4) and S,S'-diphenylsulfimide, Ph(2)SNH 1, with sodium salts of trimesic acid (H(3)tma) in MeOH gives the 2-D coordination network [Cu(3)(Ph(2)SNH)(6)(tma)(2)] in which each trimesate is bound to three copper centres. Addition of other solvents to the reaction mixture causes a change in the shape of the network. By this route… CONTINUE READING