Homogeneous Hydrogenation Art of Nitrile Butadiene Rubber: A Review

  title={Homogeneous Hydrogenation Art of Nitrile Butadiene Rubber: A Review},
  author={Hui Wang and Lijuan Yang and Garry Llewellyn Rempel},
  journal={Polymer Reviews},
  pages={192 - 239}
Hydrogenation of nitrile butadiene rubber (NBR) is an important research topic in the field of chemical modification of unsaturated polymers. This review provides an overview of the fundamental data, challenges, and recent advances in the research area of homogeneous hydrogenation of NBR. Besides NBR and its hydrogenation product HNBR, some other important elastomers such as styrene butadiene rubber (SBR), polybutadiene rubber (BR), polystyrene-b-polybutadiene-b-polystyrene (SBS block copolymer… 

Selectively catalytic hydrogenation of nitrile-butadiene rubber using Grubbs II catalyst

Hydrogenated nitrile-butadiene rubber (H-NBR) is a high-performance elastomer with important applications in the automobile industry and petroleum field. Selectively catalytic hydrogenation of

Synthesis of Low Temperature Resistant Hydrogenated Nitrile Rubber Based on Esterification Reaction

This work provides a novel and simple preparation method for low temperature resistant HNBR, which might be used potentially in extremely cold environments.

Branched EHNBR and its properties with enhanced low-temperature performance and oil resistance

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An efficient and recyclable catalyst was prepared by depositing rhodium nanoparticles (Rh NPs) on a SiO2 support with the surface modified by 3-aminopropyl-trimethoxysilane (APTS). The obtained

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The kinetics of hydrogenation of acrylonitrile butadiene rubber (NBR) latex by the action of diimide generated by hydrazine hydrate and hydrogen peroxide in the presence of copper sulfate at low

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Herein, a systematical investigation is devoted to explore nitrile butadiene rubber (NBR) hydrogenation activity and selectivity in different organic solvents, and the dependence between reactivity



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Hydrogenation of natural rubber latex in the presence of OsHCl(CO)(O2)(PCy3)2

Hydrogenation is an important method of chemical modification, which improves the physical, chemical, and thermal properties of diene elastomers. Natural rubber latex (NRL) can be quantitatively

Improvements in the Hydrogenation of Nitrile Rubber Using Wilkinson's Catalyst

Abstract RhCl(PPh3)3 is an efficient catalyst precursor for the selective hydrogenation of C=C in acrylonitrile butadiene rubber(“nitrile rubber”, NBR). The established technology for the process

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The biphasic hydrogenations of a number of polymeric materials, polybutadiene (PBD), nitrile-butadiene rubber (NBR) and styrene-butadiene rubber (SBR), were investigated in a

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Hydrogenation of carboxylic styrene–butadiene rubber latex was carried out using hydrazine and hydrogen peroxide with ferrous sulfate as a catalyst without pressurized hydrogen and an organic