Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis.

@article{Wang2016Homochiral2P,
  title={Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis.},
  author={Xiuren Wang and Xing Han and Jie Zhang and Xiaowei Wu and Yan Liu and Yong Cui},
  journal={Journal of the American Chemical Society},
  year={2016},
  volume={138 38},
  pages={
          12332-5
        }
}
There have been breakthroughs in the development of covalent organic frameworks (COFs) with tunability of composition, structure, and function, but the synthesis of chiral COFs remains a great challenge. Here we report the construction of two-dimensional COFs with chiral functionalities embedded into the frameworks by imine condensations of enantiopure TADDOL-derived tetraaldehydes with 4,4'-diaminodiphenylmethane. Powder X-ray diffraction and computer modeling together with pore size… CONTINUE READING
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