Hiyama cross-coupling of chloro-, fluoro-, and methoxypyridyltrimethylsilanes: room-temperature novel access to functional bi(het)aryl.

Abstract

The incorporation of chloro, fluoro, or methoxy substituents on the pyridine ring of pyridyltrimethylsilanes allowed us to perform efficient Hiyama cross-coupling with various (het)aryl halides. The reactions proceeded smoothly at room temperature leading to the corresponding functional bis(het)aryl in fair to excellent yields. The presence of pyridine… (More)

Cite this paper

@article{Pierrat2005HiyamaCO, title={Hiyama cross-coupling of chloro-, fluoro-, and methoxypyridyltrimethylsilanes: room-temperature novel access to functional bi(het)aryl.}, author={Philippe Pierrat and Philippe C. Gros and Yves Fort}, journal={Organic letters}, year={2005}, volume={7 4}, pages={697-700} }