Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications.

Abstract

A new route for the synthesis of functionalized alkenylsilatranes has been developed based on ruthenium-catalyzed trans-silylation with olefins. This transformation allowed for the synthesis of new (E)-alkenylsilatranes in good yields and excellent selectivity. Experimental studies concerning the reaction mechanism were carried out and the intermediate… (More)
DOI: 10.1039/c7dt00201g

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@article{Sztorch2017HighlySS, title={Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications.}, author={Bogna Sztorch and Dawid Frąckowiak and Jadwiga Pyziak and Agnieszka Czapik and Marcin Hoffmann and Bogdan Marciniec}, journal={Dalton transactions}, year={2017}, volume={46 15}, pages={4975-4981} }