Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins.

Abstract

A small family of new chiral hybrid, diphosphorus ligands, consisting of phosphine-phosphoramidites L1 and L2 and phosphine-phosphonites L3a-c, was synthesized for the application in Rh-catalyzed asymmetric hydroformylation of heterocyclic olefins. High-pressure (HP)-NMR and HP-IR spectroscopy under 5-10 bar of syngas has been employed to characterize the… (More)
DOI: 10.1021/ja210117z

Topics

5 Figures and Tables