Highly cis-selective Rh(I)-catalyzed cyclopropanation reactions.

Abstract

The performance of recently reported highly cis-diastereoselective Rh(I) cyclopropanation catalysts has been significantly improved by a systematic study of different reaction parameters (catalyst activation, solvent, temperature, stoichiometry). The catalyst efficiency and diastereoselectivity were enhanced by changing the activating agent from AgOTf to… (More)
DOI: 10.1021/jo102140z

Topics

  • Presentations referencing similar topics